Chem. Sci.
 2025
DOI: 10.1039/d4sc06138a
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Iridium trihydride and tetrahydride complexes and their role in catalytic polarisation transfer from parahydrogen to pyruvate

Ben. J. Tickner,
Simon B. Duckett

Abstract: This work details how the unusual iridium tetrahydride [Ir(H)4(IMes)(sulfoxide)]Na can be formed in a solvent dependent reaction of [IrCl(COD)(IMes)] with sulfoxide (dimethyl or methylphenyl), base, and H2. In the case...

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