Iron-catalyzed direct amination of azoles using formamides or amines as nitrogen sources in air

Wang, Jian; Hou, Ji‐Ting; Wen, Jun; Zhang, Ji; Yu, Xiao‐Qi

doi:10.1039/c0cc05811d

Cited by 139 publications

(50 citation statements)

References 35 publications

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“…[30] Imidazole was used as an additive in this catalytic system and oxygen in air was employed during the transformation process. A plausible mechanism was proposed and is presented in Scheme 17.…”

Section: Serving As a Source Of Dimethylamine In Amination Reactionsmentioning

confidence: 99%

N,N‐Dimethylformamide: A Multipurpose Building Block

2012

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Often used as a common solvent for chemical reations and utilized widely in industry as a reagent, N,N-dimethylformamide (DMF) has played an important role in organic synthesis for a long time. Numerous highly useful articles and reviews discussing its utilizations have been published. With a focus on the performance of DMF as a multipurpose precursor for various units in numerous reactions, this Minireview summarizes recent developments in the employment of DMF in the fields of formylation, aminocarbonylation, amination, amidation, and cyanation, as well as its reaction with arynes.

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Section: Serving As a Source Of Dimethylamine In Amination Reactionsmentioning

confidence: 99%

N,N‐Dimethylformamide: A Multipurpose Building Block

2012

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“…Iron-catalyzed direct amination was developed in 2011 by Yu and co-workers (213). They used FeCl 3 -benzoxazoles with formamide and different secondary amines as nitrogen sources via decarbonylation (Table XXXI).…”

Section: Direct C-n Bond Formation Via C-h Oxidationmentioning

confidence: 99%

Iron Catalysis in Synthetic Chemistry

Rana

Modak

Maity

et al. 2014

Progress in Inorganic Chemistry: Volume 59

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“…The palladium-catalyzed cross-coupling of aryl amine with aryl halide and pseudo halide is most popular method in this transformation [18,19]. Besides palladium, other catalytic systems using manganese [20], iron [21], cobalt [22], nickel [23,24], copper [25,26], indium [27], gold [28] and rhodium [29] have also been reported for the same purpose. However, among these transition metal complexes, cadmium complexes with oxazoline-based ligands have not received much attention [30].…”

Section: Introductionmentioning

confidence: 99%