2010
DOI: 10.1016/j.ccr.2010.01.005
|View full text |Cite
|
Sign up to set email alerts
|

Iron–dinitrogen coordination chemistry: Dinitrogen activation and reactivity

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
1
1
1

Citation Types

4
216
0

Year Published

2010
2010
2020
2020

Publication Types

Select...
6
4

Relationship

0
10

Authors

Journals

citations
Cited by 225 publications
(223 citation statements)
references
References 124 publications
4
216
0
Order By: Relevance
“…In this reaction system, up to 34 equiv. of N(SiMe 3 ) 3 Recently, the preparation of Fe-N 2 complexes and their stoichiometric reactivity have been intensively studied [24][25][26][27] , but the Fe-catalysed transformation of N 2 by using Fe-N 2 complexes has not yet been reported until now 28 . We believe that the results described here provide valuable and useful information to develop the Fe-catalysed transformation of N 2 .…”
Section: Discussionmentioning
confidence: 99%
“…In this reaction system, up to 34 equiv. of N(SiMe 3 ) 3 Recently, the preparation of Fe-N 2 complexes and their stoichiometric reactivity have been intensively studied [24][25][26][27] , but the Fe-catalysed transformation of N 2 by using Fe-N 2 complexes has not yet been reported until now 28 . We believe that the results described here provide valuable and useful information to develop the Fe-catalysed transformation of N 2 .…”
Section: Discussionmentioning
confidence: 99%
“…In this context, most of the effort has been focused on molybdenum and iron systems [14][15][16][17][18]. Two major strategies for catalytic N2 activation by homogeneous systems were developed: reductive protonation to yield ammonia and reductive silylation to yield silylamines ( Figure 1).…”
Section: Introductionmentioning
confidence: 99%
“…Although the site(s) of N 2 reduction remain(s) uncertain, a body of evidence that includes biochemical, spectroscopic, and computational studies on FeMoco point to a belt Fe center as a plausible candidate (2,(9)(10)(11)(12)(13). In a scenario in which N 2 binds terminally to one of the belt Fe centers, the N 2 ligand would initially be coordinated trans to the interstitial C atom ( Fig.…”
mentioning
confidence: 99%