2013
DOI: 10.1002/chem.201201743
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Iron Metal–Organic Frameworks MIL‐88B and NH2‐MIL‐88B for the Loading and Delivery of the Gasotransmitter Carbon Monoxide

Abstract: Crystals of MIL-88B-Fe and NH2-MIL-88B-Fe were prepared by a new rapid microwave-assisted solvothermal method. High-purity, spindle-shaped crystals of MIL-88B-Fe with a length of about 2 μm and a diameter of 1 μm and needle-shaped crystals of NH2-MIL-88B-Fe with a length of about 1.5 μm and a diameter of 300 nm were produced with uniform size and excellent crystallinity. The possibility to reduce the as-prepared frameworks and the chemical capture of carbon monoxide in these materials was studied by in situ ul… Show more

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Cited by 151 publications
(132 citation statements)
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“…Indeed, we have recently demonstrated the advantage of photoactive MOFs for the controlled delivery of biologically active nitric oxide (NO) molecules at the cellular level. 24,25 Although there has been only one example of CO-releasing MOF, 26 in which CO gas is first adsorbed onto open metal sites and then steadily released through ligand exchange reaction with water in physiological media, to the best of our knowledge, highly controllable release of CO from MOFs is yet to be achieved.…”
Section: Introductionmentioning
confidence: 99%
“…Indeed, we have recently demonstrated the advantage of photoactive MOFs for the controlled delivery of biologically active nitric oxide (NO) molecules at the cellular level. 24,25 Although there has been only one example of CO-releasing MOF, 26 in which CO gas is first adsorbed onto open metal sites and then steadily released through ligand exchange reaction with water in physiological media, to the best of our knowledge, highly controllable release of CO from MOFs is yet to be achieved.…”
Section: Introductionmentioning
confidence: 99%
“…These include NO-delivering MOFs, which have been evaluated as vasorelaxants [113], CO-releasing MOFs, which release CO with half-lives in the range of minutes to hours [114], and H 2 S-releasing MOFs, which can retain H 2 S in their pores for up to 1 year and exhibit vasodilatory activity in vitro [115]. Other hybrid organic/inorganic materials have also been reported, including NO-releasing silica particles [116] and zeolites [117], and CO-releasing silica nanoparticles [118] and nanodiamonds [119].…”
Section: Methodsmentioning
confidence: 99%
“…Tissue-targeting materials. Unlike the micelle-and NP-based carriers of CORMs, dendrimers, 59 copolymers, 60 and porous materials [61][62][63] have been utilized as tissue-targeting scaffolds. These scaffolds are expected to accumulate passively and selectively in tumor tissues as a result of the enhanced permeability and retention effect.…”
Section: Synthetic Polymer Materialsmentioning
confidence: 99%
“…Porous materials including mesoporous silica nanoparticles (MSNPs), 61 nanoporous fibers (NFs), 62 and metal organic frameworks (MOFs) 63 have been used to incorporate CORMs. Mascharak and co-workers demonstrated that fac-[Mn( pqa)-(CO) 3 ]ClO 4 can be incorporated into pores of Al-MCM-41 MSNPs (Fig.…”
Section: Synthetic Polymer Materialsmentioning
confidence: 99%
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