“…The corner Fe atoms (Fe c ) are surrounded by 12 nearest neighbors and the face-center ones (Fe f ) have two N atoms as nearest neighbors. This simple crystallographic structure makes it attractive for fundamental investigation, both theoretical [4] and experimental [5,6]. In order to improve the magnetic properties and the chemical stability of ␥ -Fe 4 N, one has synthesized and studied (Fe,M) 4 N by the substitution of a second transition metal M (M = Ni, Sn, Cu,.…”