Linear Temporal Logic (LTL) is one of the most popular temporal logics and comes into play in a variety of branches of computer science. Among the various reasons of its widespread use there are its strong foundational properties: LTL is equivalent to counter-free ω-automata, to star-free ω-regular expressions, and (by Kamp's theorem) to the first-order theory of one successor (S1S [FO]). Safety and co-safety languages, where a finite prefix suffices to establish whether a word does not belong or belongs to the language, respectively, play a crucial role in lowering the complexity of problems like model checking and reactive synthesis for LTL. Safety-LTL (resp., coSafety-LTL) is a fragment of LTL where only universal (resp., existential) temporal modalities are allowed, that recognises safety (resp., co-safety) languages only.The main contribution of this paper is the introduction of a fragment of S1S[FO], called Safety-FO, and of its dual coSafety-FO, which are expressively complete with respect to the LTL-definable safety and co-safety languages. We prove that they exactly characterize Safety-LTL and coSafety-LTL, respectively, a result that joins Kamp's theorem, and provides a clearer view of the characterization of (fragments of) LTL in terms of first-order languages. In addition, it gives a direct, compact, and self-contained proof that any safety language definable in LTL is definable in Safety-LTL as well. As a by-product, we obtain some interesting results on the expressive power of the weak tomorrow operator of Safety-LTL, interpreted over finite and infinite words. Moreover, we prove that, when interpreted over finite words, Safety-LTL (resp. coSafety-LTL) devoid of the tomorrow (resp., weak tomorrow ) operator captures the safety (resp., co-safety) fragment of LTL over finite words.We then investigate some formal properties of Safety-FO and coSafety-FO: (i) we study their succinctness with respect to their modal counterparts, namely, Safety-LTL and coSafety-LTL; (ii) we illustrate an important practical application of them in the context of reactive synthesis; (iii) we compare them with expressively equivalent first-order fragments.Last but not least, we provide different characterizations of the (co-)safety fragment of LTL in terms of temporal logics, automata, and regular expressions.