“…Cosalite, pyrrhotite, bismuthinite, petzite, lillianite, proustite, pyrargyrite, argentite, jalpaite, stephanite and native gold are also included. Moreover, secondary minerals like goethite, covellite, arseniosiderite, pyrolusite, manganite, manganosite and cryptomelane contribute to the Fe and Mn content in the sediments resulting by the weathering of the surrounding rocks and the mineralizations that they comprise (Arvanitidis et al, 1989;Vavelidis et al, 1996a, b;Vavelidis et al, 1997;Melfos et al, 2008;Brun and Sokoutis, 2007;Fornadel et al, 2011). As Palea Kavala river flows towards the exit of its catchment area, it passes through extensive agricultural cultivated lands that grow on the Quaternary formations of the area and finally enters the sedimentary deposits of the Philippoi plain (Fig.…”