Estimation of the liquid phase heat capacity of ionic
liquids (ILs)
is necessary in order to select and design the optimum ILs for specific
industrial applications, particularly those involving thermal storage
and heat transfer. Most attempts at estimating the heat capacity (at
the constant pressure) of ILs have followed the group contribution
model (GCM) approach, but these have involved the use of limited databases
and cannot be applied to a wide range of ILs. In this study, an extensive
database of over 11500 data points with 273 unique ILs, made up of
155 unique cations and 74 unique anions, was compiled and used to
assess three commonly used GCMs. GCM-1 is less complicated than the
other two in terms of its mapping parameters but is more restricted
in terms of its applicability. GCM-2 and GCM-3 are more complex and
have been further improved by incorporating additional functional
groups and indirect parameters. The results have shown that GCM-2
and GCM-3 have performed better than GCM-1 in terms of their mean
absolute percentage error (MAPE) (2.37% for GCM-1, 2.27% for GCM-2,
and 2.17% for GCM-3) and enable heat capacity prediction for a wider
range of ILs.