2023
DOI: 10.1021/acs.iecr.3c00804
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Isobaric Vapor–Liquid Equilibrium Prediction from Excess Molar Enthalpy Using Cubic Equations of State and PC-SAFT

Abstract: Vapor−liquid equilibrium (VLE) data, essential for an accurate design of distillation columns, are not always readily available. This work has systematically assessed the feasibility of determining VLE data based on excess molar enthalpy (h E ) results. Twelve cubic Equation of State (cEoS) models combined with eight mixing rules and the Perturbed Chain Statistical Associating Fluid Theory (PC-SAFT) have been assessed. cEoS models are robust and applicable to a significant number of solvent families, while the… Show more

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