2012
DOI: 10.1177/204124791200300202
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Isocyanate Modification of Wood Fiber in Enhancing the Performance of its Composites with High Density Polyethylene

Abstract: This study is focused on the modification of wood fiber by using a reactive diisocyanate (toluene diisocyanate, TDI) linker to couple wood fiber with cetyl alcohol and the investigation of its effects on mechanical properties of wood fiber–HDPE composites. The reaction of TDI with wood fiber and then cetyl alcohol resulted in the formation of new urethane bonds assessed by FTIR analysis. Therefore, TDI ended cetyl alcohol was used as a coupling agent in the preparation of wood fiber/ HDPE composite. The outcom… Show more

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Cited by 11 publications
(13 citation statements)
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“…Isocyanate treated fiber-based composites possess good mechanical [63,64], thermal conductivity [65] and melt flow [66]. Permanganate treatment, sodium chlorite treatment, and stearic acid treatment are the other methods that are commonly used to modify the surface properties of natural fibers [67].…”
Section: Chemical Treatment Methodsmentioning
confidence: 99%
“…Isocyanate treated fiber-based composites possess good mechanical [63,64], thermal conductivity [65] and melt flow [66]. Permanganate treatment, sodium chlorite treatment, and stearic acid treatment are the other methods that are commonly used to modify the surface properties of natural fibers [67].…”
Section: Chemical Treatment Methodsmentioning
confidence: 99%
“…Such an approach was used by Arjmand et al (2012) during the modification of softwood fibers with TDI. First, the authors treated fibers with sodium hydroxide to remove any residual waxes and oils and activate the hydroxyl groups present on the surface.…”
Section: Filler-based Strategiesmentioning
confidence: 99%
“…Possible reaction of a TDI with wood fiber and b free isocyanate group in TDI-treated wood fiber with cetyl alcohol(Arjmand et al 2012) …”
mentioning
confidence: 99%
“…Research findings on isocyanate treated natural fibers and its influence toward the performance on NFPCs is discussed below. [ 310–320 ]…”
Section: Resolving Challenges With Modification Of Fiber and Matrixmentioning
confidence: 99%
“…Moisture's absorption of 20% TDI treated composites displayed a reduction by about 43%. [ 314 ] Hemp fiber composites treated with TMI‐7‐20 prove to be an optimal condition for tensile strength and it is higher than the control by 34.7%, whereas with regard to flexural strength composites treated with TMI‐3‐10 combination proves to be an optimal condition. TMI treatments do not have any influence toward the flexural modulus and remain same with that of control.…”
Section: Resolving Challenges With Modification Of Fiber and Matrixmentioning
confidence: 99%