Isolation of Phytoconstituents and Evaluation of Anti-inflammatory Activity of the Leaves of Abelmoschus manihot

The phosphine ligand mediated palladium catalyzed alkoxycarbonylation of alkenes was investigated with the objective of attaining good linear selectivity for the ester. The effect of various parameters such as solvents, additives, palladium precursors, CO pressures, and alkenes of various structural complexities were examined. The results revealed the importance of using a Lewis acid such as SnCl2 or Ti(O(i)Pr)4 in combination with a monodentate ligand such CYTOP 292 or P(p-anisyl)3 to enhance the regioselectivity for the linear isomers in the range of 70-96%.

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Isolation of Phytoconstituents and Evaluation of Anti-inflammatory Activity of the Leaves of Abelmoschus manihot

Cited by 2 publications

References 19 publications

Chemical constituents from Dicraenthus zehnderi H. hess and their chemotaxonomic significance

Chemical constituents from Dicraenthus zehnderi H. hess and their chemotaxonomic significance

Pd-Catalyzed Regioselective Alkoxycarbonylation of 1-Alkenes Using a Lewis Acid [SnCl₂ or Ti(OⁱPr)₄] and a Phosphine

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Isolation of Phytoconstituents and Evaluation of Anti-inflammatory Activity of the Leaves of Abelmoschus manihot

Cited by 2 publications

References 19 publications

Chemical constituents from Dicraenthus zehnderi H. hess and their chemotaxonomic significance

Chemical constituents from Dicraenthus zehnderi H. hess and their chemotaxonomic significance

Pd-Catalyzed Regioselective Alkoxycarbonylation of 1-Alkenes Using a Lewis Acid [SnCl2 or Ti(OiPr)4] and a Phosphine

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Product

Resources

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Pd-Catalyzed Regioselective Alkoxycarbonylation of 1-Alkenes Using a Lewis Acid [SnCl₂ or Ti(OⁱPr)₄] and a Phosphine