Isolation of Sensing Units and Adsorption Groups Based on MOF-on-MOF Hierarchical Structure for Both Highly Sensitive Detection and Removal of Hg²⁺

Abstract

Bifunctional materials have attracted ongoing interest in the field of detection and removal of contaminants because of their integration of two functions, but they exhibit commonly exceptional performance in only one of these two aspects. The interaction between the two functional units of the bifunctional materials may compromise their sensing and adsorption abilities. Guided by the concept of domain building blocks (DBBs), a hierarchical metal−organic framework (MOF)-on-MOF hybrid was designed by growing gold nanoclusters (AuNCs)-embedded zeolitic imidazolate framework 8 (AuNCs/ZIF-8) on the surface of Zr-MOF (UiO-66-NH 2 ) for the simultaneous detection and removal of Hg 2+ . In the hybrid, the amino groups (−NH 2 ) and AuNCs�which were the adsorption groups and sensing units, respectively, were isolated from each other. Specifically, the adsorption groups (−NH 2 ) were assembled in the inner UiO-66-NH 2 layer, while the sensing units (AuNCs) were confined in the outer ZIF-8 layer. This hierarchical structure not only spatially hindered the electron transfer between these two units but also triggered the aggregation-induced emission of AuNCs because of the confinement of ZIF-8 on the AuNCs, thus changing the fluorescence of AuNCs from quenching to enhancement. The newly prepared UiO-66-NH 2 @AuNCs/ZIF-8 hybrid, as expected, showed an ultralow detection limit (0.42 ppb) and a high adsorption capacity (129.9 mg•g −1 ) for Hg 2+ . Overall, this work provides a feasible approach to improve the integrated performance of MOF-based composites based on DBBs.

Fluorophore branching boosted photo-induced energy transfer in UiO-66 for ultrasensitive and instant hydrazine sensing

“…Benefiting from their diverse functional sites, open metal sites, and photo-responsive sites, metal organic frameworks (MOFs) have been extensively explored for various applications, such as photocatalysis, 1–3 gas capture, 4–6 energy storage, 7,8 and fluorescent sensing. 9–11 Specifically, due to their rich porosity, MOFs have excellent adsorption and enrichment effects, 12–15 which can accelerate energy transfer and excited state migration with analytes, leading to signal amplification in fluorescent sensing. 16 It is known that photoluminescence mechanisms could directly determine the sensing performance of MOFs, and great efforts have been devoted to understanding them.…”