Isomerism and interpenetration in hydrogen-bonded network structures

Burke, Nichola J.; Burrows, Andrew D.; Mahon, Mary F.; Warren, John E.

doi:10.1039/b712678f

Cited by 5 publications

(3 citation statements)

References 22 publications

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“…It is quite the opposite case when the sulfonic function (−SO 3 H) is applied. , Naphthalene-1,5-disulfonic acid [H 2 NDS(1,5)] is frequently used as an organic building unit for supramolecular assemblies − and in coordination chemistry, as a counterion , or coordination polymer linker. − The CSD search provided 194 structures into which the NDS(1,5) moiety is incorporated. In general, sulfonic acids have quite different properties from carboxylic acids.…”

Section: Introductionmentioning

confidence: 99%

Chains, Layers, Channels, and More: Supramolecular Chemistry of Potent Diphosphonic Tectons with Tuned Flexibility. The Generation of Pseudopolymorphs, Polymorphs, and Adducts

Białek

Zarȩba

Janczak

et al. 2013

Crystal Growth & Design

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c a c i d [C 10 H 6 (PO 3 H 2 ) 2 , H 4 NDP(1,5), 1] and its more flexible counterp a r t , n a p h t h a l e n e -1 , 5 -b i s ( m e t h y l p h o s p h o n i c ) a c i d [C 10 H 6 (CH 2 PO 3 H 2 ) 2 , H 4 NDP(1C,5C), 2], have been synthesized, characterized, and used as building blocks in supramolecular assemblies with 4-(N,N-dimethylamino)pyridine (DMAP) and morpholine. The two acids generate two distinct solvatomorphs each, with and without dimethyl sulfoxide (DMSO) molecules. The two adducts of H 4 NDP(1,5) with DMAP (3A and 3B) reveal conformational polymorphism caused by the rotation of phosphonic groups. The two adducts of H 4 NDP(1C,5C) show unexpected structural diversity, generating a symmetric hydrogen bond and creating a layered structure, 4A, or a channel structure, 4B. The adducts of both acids with morpholine (5A and 5B) allow for observing the influence of the conformational flexibility of the acids on the dimensionality of a final hydrogen bond network, which is in general higher for H 4 NDP(1C,5C). The structural motifs and trends are analyzed in terms of the geometric criteria of these interactions. For the first time, Hirshfeld surface analysis has also been applied for the investigation of supramolecular interactions of phosphonic acids in different protonation states.

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Section: Introductionmentioning

confidence: 99%

Chains, Layers, Channels, and More: Supramolecular Chemistry of Potent Diphosphonic Tectons with Tuned Flexibility. The Generation of Pseudopolymorphs, Polymorphs, and Adducts

Białek

Zarȩba

Janczak

et al. 2013

Crystal Growth & Design

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“…Although -polonium nets have been widely reported in coordination polymers, only in a few cases does their construction involve hydrogen-bonding interactions (e.g. Burke et al, 2008;Roesky & Andruh, 2003).…”

Section: Commentmentioning

confidence: 99%

Poly[diaqua[μ-1,4-bis(imidazol-1-ylmethyl)benzene-κ²N³:N^3′](μ-trans-cyclohexane-1,4-carboxylato-κ²O¹:O⁴)manganese(II)]: a three-dimensional hydrogen-bonding α-polonium net

Wang

et al. 2009

Acta Crystallogr C

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In the title coordination compound, [Mn(C8H10O4)(C14H14N4)(H2O)2]n, each Mn(II) centre occupies an inversion centre. The 1,4-bis(imidazol-1-ylmethyl)benzene (1,4-bix) ligand and the trans-cyclohexane-1,4-dicarboxylate dianion (chdc) both function in bridging modes, linking adjacent Mn(II) centres into a two-dimensional four-connected (4,4) network. These two-dimensional layers are stacked in a parallel mode. Hydrogen bonds between water molecules and carboxylate O atoms link neighbouring (4,4) networks, yielding a three-dimensional alpha-polonium net.

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“…Assembling metal complexes through hydrogen bonds to create extended solids between the supramolecular chemistry of the organosulfonate group has achieved progress [34][35][36][37][38]. There are some examples of main group and transition metal arenesulfonates, broadly dis-*Corresponding author.…”

Section: Introductionmentioning

confidence: 99%

Interesting structures of self-assembled gadolinium coordination polymers with tuned stoichiometric ratios

Liu

Wang

et al. 2013

Journal of Coordination Chemistry

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Hydrothermal reactions of gadolinium(III) salts with 2,6-naphthalenedisulfonate (nds) and 1,10-phenanthroline with varying mole ratios led to five different compounds, {Gd(phen)(nds)(OH)} n (1), {[Gd 2 (phen) 4 (nds) 3 In the case of 1, nds coordinates as η 2 μ 2 -η 2 μ 2 bridging ligand to adjacent dimers, leading to a three-dimensional network. In 2, nds bridges with each SO 3 À coordinated as a η 3 μ 1 -bridging group, creating a two-dimensional polymer. For 3, 1-D infinite chains with dinuclear units connected by nds results in a 3-D framework based on hydrogen-bond interactions. 0-D 4 and 1-D 5 contain dinuclear clusters, which are further assembled into 3-D supramolecular networks via weak hydrogen bonds and aromatic packing interactions.

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Isomerism and interpenetration in hydrogen-bonded network structures

Cited by 5 publications

References 22 publications

Chains, Layers, Channels, and More: Supramolecular Chemistry of Potent Diphosphonic Tectons with Tuned Flexibility. The Generation of Pseudopolymorphs, Polymorphs, and Adducts

Chains, Layers, Channels, and More: Supramolecular Chemistry of Potent Diphosphonic Tectons with Tuned Flexibility. The Generation of Pseudopolymorphs, Polymorphs, and Adducts

Poly[diaqua[μ-1,4-bis(imidazol-1-ylmethyl)benzene-κ²N³:N^3′](μ-trans-cyclohexane-1,4-carboxylato-κ²O¹:O⁴)manganese(II)]: a three-dimensional hydrogen-bonding α-polonium net

Interesting structures of self-assembled gadolinium coordination polymers with tuned stoichiometric ratios

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Isomerism and interpenetration in hydrogen-bonded network structures

Cited by 5 publications

References 22 publications

Chains, Layers, Channels, and More: Supramolecular Chemistry of Potent Diphosphonic Tectons with Tuned Flexibility. The Generation of Pseudopolymorphs, Polymorphs, and Adducts

Chains, Layers, Channels, and More: Supramolecular Chemistry of Potent Diphosphonic Tectons with Tuned Flexibility. The Generation of Pseudopolymorphs, Polymorphs, and Adducts

Poly[diaqua[μ-1,4-bis(imidazol-1-ylmethyl)benzene-κ2N3:N3′](μ-trans-cyclohexane-1,4-carboxylato-κ2O1:O4)manganese(II)]: a three-dimensional hydrogen-bonding α-polonium net

Interesting structures of self-assembled gadolinium coordination polymers with tuned stoichiometric ratios

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Poly[diaqua[μ-1,4-bis(imidazol-1-ylmethyl)benzene-κ²N³:N^3′](μ-trans-cyclohexane-1,4-carboxylato-κ²O¹:O⁴)manganese(II)]: a three-dimensional hydrogen-bonding α-polonium net