2021
DOI: 10.1039/d1se00771h
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Isomerization of glucose to fructose catalyzed by metal–organic frameworks

Abstract: The isomerization reaction of glucose to fructose was studied using five selected metal-organic frameworks (MOFs) as catalysts and a mixture of γ-valerolactone and 10% H2O as the solvent. MOFs with...

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Cited by 25 publications
(28 citation statements)
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“…The three synthesized MOFs (MIL-53(Cr), CuBTC, and MIL-101(Cr)) and commercial MOF samples were characterized by XRD and FTIR (see Figures S1 and S2, Supporting Information, respectively); in all cases, the structure was similar to previously published structures , [17] . [42][43][44][45][46] The tungsten content of the prepared POM@MOF determined by chemical analysis is recompiled in Table 1.…”
Section: Catalyst Preparation and Characterizationsupporting
confidence: 58%
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“…The three synthesized MOFs (MIL-53(Cr), CuBTC, and MIL-101(Cr)) and commercial MOF samples were characterized by XRD and FTIR (see Figures S1 and S2, Supporting Information, respectively); in all cases, the structure was similar to previously published structures , [17] . [42][43][44][45][46] The tungsten content of the prepared POM@MOF determined by chemical analysis is recompiled in Table 1.…”
Section: Catalyst Preparation and Characterizationsupporting
confidence: 58%
“…Tandem reactions, which enable two‐step reactions in one pot, [ 18 ] could be a very interesting route to produce HMF, [ 19 ] which is why it is important to find a bi‐functional catalyst for the isomerization reaction and, then, for the dehydration reaction of fructose. The isomerization reaction is catalyzed by Lewis acid‐type centers, and metal–organic frameworks (MOFs) can act as Lewis acids ,[ 17 ] . [ 20 ] Then, the second reaction (dehydration of fructose to HMF) requires Brønsted‐acid catalysts, [ 3 ] and in this case, a polyoxometalate (POM) was selected.…”
Section: Introductionmentioning
confidence: 99%
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