1996
DOI: 10.1006/jcht.1996.0008
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Isopiestic determination of the osmotic coefficients of Lu2(SO4)3(aq) and H2SO4(aq) at the temperatureT= 298.15 K, and review and revision of the thermodynamic properties of Lu2(SO4)3(aq) and Lu2(SO4)3·8H2O(cr)a

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Cited by 31 publications
(63 citation statements)
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“…That experiment was successful, but the ZnSO 4 (aq) began crystallizing as soon as it cooled from T = 298.15 K to the laboratory temperature of T ∼ 297 K. f Water was added to the ZnSO 4 samples to dissolve the crystals, and all four samples were then diluted for the final experiment of this series. (32) who also listed the "n − 1" standard deviations. Experiments A and B were based on samples of previously fused NaCl(s).…”
Section: Methodsmentioning
confidence: 99%
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“…That experiment was successful, but the ZnSO 4 (aq) began crystallizing as soon as it cooled from T = 298.15 K to the laboratory temperature of T ∼ 297 K. f Water was added to the ZnSO 4 samples to dissolve the crystals, and all four samples were then diluted for the final experiment of this series. (32) who also listed the "n − 1" standard deviations. Experiments A and B were based on samples of previously fused NaCl(s).…”
Section: Methodsmentioning
confidence: 99%
“…The isopiestic method has been described in detail by Rard and Platford. (16) Isopiestic apparatuses at both laboratories have fan-like devices attached to their copper heat-transfer blocks, (11,31,32) which provide vapor stirring during the equilibrations. Air was removed from these apparatuses prior to starting each equilibration as described elsewhere.…”
Section: Methodsmentioning
confidence: 99%
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“…Based on the cation and anion impurity analysis results reported by the supplier, other anions and cations that were present were in insignificant amounts, and is likely that most of the reported 0.1 % impurities are actually residual water. Dehydration experiments for two commercials samples of NaCl(s) [Rard, 1996, Table 2] showed the presence of 0.1-0.15 mass-% residual water in the original samples, which is not completely removed until the NaCl samples are heated to ≈500 °C. Thus, for NaCl the only significant impurity is likely to be residual water.…”
Section: Source Chemicals and Preparation Of The Solutionsmentioning
confidence: 99%