Isothermal VLE and V^E at 303.15 K for the Binary and Ternary Mixtures of Di-isopropyl Ether (DIPE) + 1-Propanol + 2,2,4-Trimethylpentane

Abstract

Isothermal vapor-liquid equilibrium (VLE) data at 303.15 K are reported for the binary systems of di-isopropyl ether (DIPE) + 1-propanol, DIPE + 2,2,4-trimethylpentane, and 1-propanol + 2,2,4-trimethylpentane and also for the ternary system of DIPE + 1-propanol + 2,2,4-trimethylpentane by using headspace gas chromatography. Additionally, the excess molar volumes (V E ) at 303.15 K for the same systems were also determined by measured densities. The experimental binary and ternary VLE data were correlated with G E model equations and the V E were correlated with the Redlich-Kister equation for binary systems and the Cibulka equation for ternary system, respectively.

Viscosities of Binary Mixtures Containing Isomeric Chlorobutanes and Diisopropylether: Experimental and Predicted Values

“…This work follows our study of liquid mixtures containing cyclic ethers and chloroalkanes [1][2][3][4]. The study of these mixtures is important since they are normally used in the petroleum industry; the reformulation of gasoline includes certain oxygenated compounds such as ethers [5][6][7]. These oxygenated compounds are added to improve the octane rating and the pollution-reducing capability of gasoline.…”

Isothermal Vapor−Liquid Equilibrium at 333.15 K and Excess Molar Volumes, Refractive Indices, and Excess Molar Enthalpies at 303.15 K for the Binary and Ternary Mixtures of Di-isopropyl Ether, Ethanol, and 2,2,4-Trimethylpentane

“…Therefore, we have reported so far the phase equilibria and mixture properties for binary and ternary systems that involve gasoline additives. [2][3][4] As a continuous work on the phase equilibrium and mixture properties for gasoline additives, we report vapor-liquid equilibrium (VLE) data at 333.15 K for the binary systems {DIPE + ethanol} and {DIPE + 2,2,4-trimethylpentane} and also for the ternary system {DIPE + ethanol + 2,2,4-trimethylpentane} using headspace gas chromatography (HSGC). The experimental binary VLE data were correlated with common G E models (Margules, van Laar, Wilson, nonrandom two-liquid (NRTL), and UNIQUAC), while the experimental ternary VLE data were correlated with Wilson, NRTL, and UNIQUAC models.…”

High Pressure Volumetric Properties of the Binary Mixtures Di-isopropyl Ether + 2,2,4-Trimethylpentane

“…Experimental values of excess volumes, V E , of x DIPE + (1 – x ) 2,2,4-trimethylpentane at 0.1 MPa as a function of the mole fraction for different temperature T : ◇, 293.15 K; □, 313.15K; △, 333.15 K. Literature references: ●, Blanco et al 298.15 K; ⧫, Chen and Tu at 288.15 K; ▲, Chen and Tu at 298.15 K; ○, Chen and Tu at 308.15 K; ■, Suresh Reddy et al at 303.15 K; ×, Hwang et al at 303.15 K; +, Kim et al at 303.15 K. () Redlich–Kister’s eq .…”