Isotope effect on ultrafast charge-transfer-to-solvent reaction from I− to water in aqueous NaI solution

Suzuki, Yoshiichi; Shen, Huan; Tang, Ying; Kurahashi, Naoya; Sekiguchi, K.; Mizuno, Tomoya; Suzuki, Toshinori

doi:10.1039/c0sc00650e

Cited by 39 publications

(67 citation statements)

References 57 publications

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“…In an attempt to probe interfacial CTTS dynamics of iodide, time-resolved photoelectron spectroscopy coupled with the liquid microject technique has recently been used. 6,[9][10][11][12][13] Results from such experiments showed that the observable dynamics are very similar to those seen in the bulk.…”

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confidence: 69%

“…A particularly useful means of initiating CTTS reactions is photoexcitation to CTTS absorption bands of certain aqueous anions. The most studied of these has been the CTTS of iodide [2][3][4][5][6][7][8][9][10][11][12][13] and a schematic of the solvation dynamics are shown in Figure 1. However, these studies have focussed on the bulk dynamics, while arguably, electron transfer reactions are of most interest at interfaces, be it on an aerosol particle, on an interstellar dust-grain, or at a water/biomolecule interface.…”

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confidence: 99%

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Charge Transfer to Solvent Dynamics at the Ambient Water/Air Interface

Nowakowski

Woods

Verlet

2016

J. Phys. Chem. Lett.

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confidence: 69%

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confidence: 99%

Charge Transfer to Solvent Dynamics at the Ambient Water/Air Interface

Nowakowski

Woods

Verlet

2016

J. Phys. Chem. Lett.

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“…92 Recent examples include study of electron attachment to nucleobases in clusters, 93,94 and charge-transfer-to-solvent reactions for I -in aqueous solution. 95 …”

Section: Time-resolved Photoelectron Spectroscopymentioning

confidence: 99%

The Study of Reactive Intermediates in Condensed Phases

2016

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Novel experimental techniques and computational methods have provided new insight into the behavior of reactive intermediates in solution. The results of these studies show that some of the earlier ideas about how reactive intermediates ought to behave in solution were incomplete or even incorrect. This perspective summarizes what the new experimental and computational methods are, and draws attention to the shortcomings that their application has brought to light in previous models. Key areas needing further research are highlighted.

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“…In this case no solute intramolecular effects need to be accounted for. Although resonant excitation is indeed a crucial factor in previous experimental studies of the CTTS dynamics, the resonance condition is rather loosely defined since photon energies vary considerably in different experiments, typically between 5.1 and 6.2 eV [13,14,15,16]. Importantly though, a significant fraction of the CTTS-state manifold, with energies fairly near the CTTS lowest state, is populated instantaneously by one-photon absorption.…”

Section: Introductionmentioning

confidence: 99%