IUPAC-NIST Solubility Data Series. 81. Hydrocarbons with Water and Seawater–Revised and Updated Part 1. C5 Hydrocarbons with Water

Abstract

The mutual solubilities and related liquid-liquid equilibria of C 10 hydrocarbons with water are exhaustively and critically reviewed. Reports of experimental determination of solubility in 20 chemically distinct binary systems that appeared in the primary literature prior to end of 2002 are compiled. For ten systems sufficient data are available to allow critical evaluation. All data are expressed as mass percent and mole fraction as well as the originally reported units. In addition to the standard evaluation criteria used throughout the Solubility Data Series, a new method based on the evaluation of the all experimental data for a given homologous series of aliphatic and aromatic hydrocarbons was used.

IUPAC-NIST Solubility Data Series. 81. Hydrocarbons with Water and Seawater—Revised and Updated. Part 10. C11 and C12 Hydrocarbons with Water

“…This point is well established, because it fits the smoothing equation for lower alkanes as presented by Maczynski and co-workers. 3,4,5,7 The points for the higher alkanes shown in Fig. 1 should be consistent with the point for undecane.…”

“…In these evaluations reported solubility values are characterized as ''Recommended, Tentative, Doubtful, or Rejected,'' based on consistency between independently determined experimental values and reference values derived from a newly developed set of smoothing equations. [3][4][5][6][7][8] Recommended values are supported by two ͑or more͒ independent experimental values and a reference value that are all in agreement. Tentative values are supported by two ͑or more͒ independent values in agreement with each other, but not with the reference value, or one experimental value in agreement with the reference value.…”

“…Detailed introductory material including explanations of the formats of compilation and evaluation, definitions of commonly used measures of solubility, and the scope of the Solubility Data Series can be found in Part 1 ͑Goral et al 7 ͒. The derivation of the smoothing equations used to calculate reference values for undecane and alkylbenzenes can be found in Parts 1 and 2.…”

“…[3][4][5][6][7] The solubilities obtained with Eq. ͑1͒ were used as the input data for these calculations.…”

Experimental and molecular modelling study of the three-phase behaviour of (propane+carbon dioxide+water) at reservoir conditions

“…[25,26]. Regarding systems consisting of various (hydrocarbons + water), it is worth highlighting the extensive work of Tsonopoulos et al [27][28][29][30][31] as well as the IUPAC-NIST reviews [32][33][34][35][36][37][38][39][40], albeit both studies focused on heavier hydrocarbons than propane. For completeness, previous work on the (propane + water) mixture is here briefly reviewed.…”