We present six epochs of spectropolarimetric observations and one epoch of spectroscopy of the Type Ib SN iPTF 13bvn. The epochs of these observations correspond to −10 to +61 days with respect to the r-band light curve maximum. The continuum is intrinsically polarised to the 0.2-0.4% level throughout the observations, implying asphericities of ∼10% in the shape of the photosphere. We observe significant line polarisation associated with the spectral features of Ca II IR3, He I/Na I D, He I λλ6678, 7065, Fe II λ4924 and O I λ7774. We propose that an absorption feature at ∼ 6200Å, usually identified as Si II λ6355, is most likely to be high velocity Hα at −16, 400km s −1 . Two distinctly polarised components, separated in velocity, are detected for both He I/Na I D and Ca II IR3 , indicating the presence of two discrete line forming regions in the ejecta in both radial velocity space and in the plane of the sky. We use the polarisation of He I λ5876 as a tracer of sources of non-thermal excitation in the ejecta; finding that the bulk of the radioactive nickel was constrained to lie interior to ∼ 50 − 65% of the ejecta radius. The observed polarisation is also discussed in the context of the possible progenitor system of iPTF 13bvn, with our observations favouring the explosion of a star with an extended, distorted envelope rather than a compact Wolf-Rayet star.