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Karpenko, S. V.; Kyarov, A. Kh.; Temrokov, A. I.

doi:10.1023/a:1021964330232

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2006

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“…Note that all of the studies referred to above related to crystals of infinitely large size at a temperature of 0 K. In [10,11], the authors studied the effect of the surface contribution to the thermodynamic potential of crystal on the properties of B1-B2 transition for a number of alkali halide crystals. This paper is devoted to the study of regularities of polymorphous transformations in ionic crystals at temperatures other than absolute zero.…”

Section: Introductionmentioning

confidence: 99%

Simulation of structural phase transitions in ionic crystals under conditions of high pressures and temperatures

Karpenko

2006

High Temp

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Structural phase transitions of the B1-B2 type in alkali halide crystals are investigated at a temperature other than 0 K. The pressure of B1-B2 phase transition is calculated as a function of temperature. The calculated pressure of B1-B2 transition in these crystals is weakly and almost linearly dependent on temperature. For a number of ionic crystals, the p 0 (T) curve has a maximum at some value of temperature.

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Section: Introductionmentioning

confidence: 99%