Intelligent reflecting surface (IRS) is a promising technology to deploy reconfigurable and cost-effective nextgeneration wireless communication systems. In this work, we investigate the performance of an IRS-aided two-way communication network over Rayleigh fading channels, where downlink and uplink transmission between the base station and the user equipment is established in full-duplex mode. We take into account the impact of residual self-interference (RSI), which results from imperfect self-interference cancellation. We derive the analytical expressions of outage probability (OP), asymptotic OP, and obtain diversity order of the system. We also derive ergodic capacity in terms of the Meijer-G function. Further, we derive the analytical expressions of average symbol error rate (ASER) for general order rectangular quadrature amplitude modulation (QAM), cross QAM, and hexagonal QAM. We highlight the impact of reflecting elements, RSI, and other system parameters on the performance of the considered network and also compare the ASER of various QAM constellations. Finally, Monte-Carlo simulations validate the derived analytical expressions.