Joint solubility of lithium and aluminum bromides and iodides in ether and toluene at 25�

Arkhipov, S.M.; Mikheeva, V.I.; Pruntsev, A. E.

doi:10.1007/bf00946443

Cited by 3 publications

(2 citation statements)

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“…According to the abovementioned reaction mechanism, the introduced BIA can react with Li to form LiI. As a result of the high solubility of LiI in TEGDME, LiI may be dissolved by the TEGDME-based electrolyte, and then it participate in the decomposition of discharge product Li 2 O 2 in Li-O 2 cells . In order to verify this hypothesis, CV tests of Li-O 2 cells under an argon atmosphere with LiI or BIA were performed, and the results are shown in Figure S3.…”

Section: Resultsmentioning

confidence: 99%

Bifunctional 1-Boc-3-Iodoazetidine Enhancing Lithium Anode Stability and Rechargeability of Lithium–Oxygen Batteries

Jiang

Sun

et al. 2021

ACS Appl. Mater. Interfaces

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Lithium anode protection is an effective strategy to prohibit the continuous loss of redox mediators (RMs) resulting from the unfavorable “shuttle effect” in lithium–oxygen batteries. In this work, an in situ Li anode protection method is designed by utilizing an organic compound, 1-Boc-3-iodoazetidine (BIA), as both a RM and an additive, to form a lithium anode protective layer. The reaction between Li metal and BIA can form lithium iodide (LiI) and lithium-based organometallic. LiI can effectively reduce the charging overpotential. Meanwhile, the in situ-formed anode protection layer (lithium-based organometallic) can not only effectively prevent RMs from being reduced by the lithium metal, but also inhibit the growth of lithium dendrites. As a result, the lithium–oxygen battery with BIA shows a long cycle life of 260 cycles with a notably reduced charging potential. In particular, the battery with BIA achieves an excellent lifespan of 160 cycles at a large current density of 2000 mA g–1.

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Section: Resultsmentioning

confidence: 99%

Bifunctional 1-Boc-3-Iodoazetidine Enhancing Lithium Anode Stability and Rechargeability of Lithium–Oxygen Batteries

Jiang

Sun

et al. 2021

ACS Appl. Mater. Interfaces

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“…6,40 The addition of salt to the coagulation bath helps to solve this issue, as the dope solvent is more likely to diffuse along the gradient into the region of higher solute concentration (here, the salt) and the salt, in turn, is not significantly soluble in the dope solvent. 41 We are also able to further mitigate the effect of core and sheath solvent miscibility by the use of an RO-TN-class mixture as the core when ethanol is used as the bath solvent due to the reduced miscibility of RO-TN mixtures with ethanol compared to that of 5CB. The result is that the leaching of core material into the ethanol bath is much less favourable than the extraction of hexane into the same, thus promoting the maintenance of core contiguity.…”

Section: Fibres With Liquid Crystal Coresmentioning

confidence: 99%

Elastic sheath–liquid crystal core fibres achieved by microfluidic wet spinning

et al. 2019

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Rare Earth Starting Materials and Methodologies for Synthetic Chemistry

Ortu

2022

Chem. Rev.

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The number of rare earth (RE) starting materials used in synthesis is staggering, ranging from simple binary metal-halide salts to borohydrides and “designer reagents” such as alkyl and organoaluminate complexes. This review collates the most important starting materials used in RE synthetic chemistry, including essential information on their preparations and uses in modern synthetic methodologies. The review is divided by starting material category and supporting ligands ( i.e. , metals as synthetic precursors, halides, borohydrides, nitrogen donors, oxygen donors, triflates, and organometallic reagents), and in each section relevant synthetic methodologies and applications are discussed.

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Joint solubility of lithium and aluminum bromides and iodides in ether and toluene at 25�

Cited by 3 publications

References 0 publications

Bifunctional 1-Boc-3-Iodoazetidine Enhancing Lithium Anode Stability and Rechargeability of Lithium–Oxygen Batteries

Bifunctional 1-Boc-3-Iodoazetidine Enhancing Lithium Anode Stability and Rechargeability of Lithium–Oxygen Batteries

Elastic sheath–liquid crystal core fibres achieved by microfluidic wet spinning

Rare Earth Starting Materials and Methodologies for Synthetic Chemistry

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