In the present paper, we investigated mathematical model of the magneto hydrodynamic flow and heat transfer in an electro-conductive polymer on the external surface of a sphere under radial magnetic field is presented. Thermal and velocity (hydrodynamic) slip are considered at the sphere surface via. modified boundary conditions. The non-dimensional, transformed boundary layer equations for momentum and energy are solved with the second order accurate implicit Keller box finite difference method under appropriate boundary conditions. Validation of the numerical solutions is achieved via benchmarking with earlier published results. The influence of Weissenberg number, magnetic body force parameter, thermal slip parameter, hydrodynamic slip parameter, stream wise variable and Prandtl number on thermo fluid characteristics are studied graphically and via tables. A weak elevation in temperature accompanies increasing Weissenberg number whereas a significant acceleration in the flow is computed near the sphere surface with increasing Weissenberg number. Increasing thermal slip strongly decreases skin friction and Nusselt number. Skin friction is also depressed with increasing magnetic body force parameter. Increasing momentum slip is observed to decrease skin friction. Nusselt number is reduced with increasing Weissenberg number. Skin friction is increased whereas Nusselt number is reduced with greater stream wise coordinate. The study is relevant to smart coating transport phenomena.