Org. Biomol. Chem.
 2024
DOI: 10.1039/d4ob00488d
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K2CO3-mediated annulation of 1,3-acetonedicarboxylates with 2-fluoro-1-nitroarenes: synthesis of indoles

Meng-Yang Chang,
Chin-Huey Ho,
Hsing-Yin Chen

Abstract: The K2CO3-mediated one-pot reaction of 1,3-acetonedicarboxylates with 2 equiv. of substituted 2-fluoro-1-nitrobenzenes has been developed to synthesize various 2,3-dicarboxylate indoles via a tandem (3 + 3 − 1) annulation pathway....

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