K4Bi2O5, a Novel Ternary Oxobismuthate(III)

Zoche, Nicola; Sievers, Rolf; Jansen, Martin

doi:10.1006/jssc.1998.7853

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“…anionen [BiO 3 ] 3± bilden dagegen abha È ngig vom Kationenradius zwei unterschiedliche Strukturtypen, wobei jeweils die Na- [8] und die K- [9] sowie die Rb- [9] und die Cs-Verbindung [7] isotyp zueinander sind. Zwischen diesen beiden Zusammensetzungen ist K 4 Bi 2 O 5 [10] mit isolierten Anionen [Bi 4 O 10 ] 8± bekannt, in dem die Bi-Koordinationsspha È ren von K 3 BiO 3 (w-Tetraeder) und KBiO 2 (w-trigonale Bipyramiden) nebeneinander auftreten.…”

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Alkalimetall-Oxoantimonate: Synthesen, Kristallstrukturen und Schwingungsspektren von ASbO2 (A = K, Rb), A4Sb2O5 (A = K, Rb, Cs) und Cs3SbO4

Hirschle

Röhr

2000

Z. anorg. allg. Chem.

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Alkalimetall-Oxoantimonate: Synthesen, Kristallstrukturen und Schwingungsspektren von ASbO2 (A = K, Rb), A4Sb2O5 (A = K, Rb, Cs) und Cs3SbO4

Hirschle

Röhr

2000

Z. anorg. allg. Chem.

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Chapter 21. New compounds and structures

Harrison¹

1999

Annu. Rep. Prog. Chem., Sect. A

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Alkaline metal oxoantimonates(III),A₃[SbO₃] (A= K or Cs)

Emmerling

Röhr

2001

Acta Crystallogr C

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The two title trialkaline trioxoantimonates(III), tripotassium trioxoantimonate(III), K(3)[SbO(3)], (I), and tricaesium trioxoantimonate(III), Cs(3)[SbO(3)], (II), crystallize in the cubic Na(3)[AsS(3)] structure type in space group P2(1)3. The structures show discrete Psi-tetrahedral [SbO(3)](3-) anions with C(3v) point-group symmetry. The Sb-O distances are 1.923 (4) A in (I) and 1.928 (2) A in (II), and the O-Sb-O bond angles are 99.5 (2) degrees in (I) and 100.4 (1) degrees in (II).

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K4Bi2O5, a Novel Ternary Oxobismuthate(III)

Cited by 3 publications

References 19 publications

Alkalimetall-Oxoantimonate: Synthesen, Kristallstrukturen und Schwingungsspektren von ASbO2 (A = K, Rb), A4Sb2O5 (A = K, Rb, Cs) und Cs3SbO4

Alkalimetall-Oxoantimonate: Synthesen, Kristallstrukturen und Schwingungsspektren von ASbO2 (A = K, Rb), A4Sb2O5 (A = K, Rb, Cs) und Cs3SbO4

Chapter 21. New compounds and structures

Alkaline metal oxoantimonates(III),A₃[SbO₃] (A= K or Cs)

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K4Bi2O5, a Novel Ternary Oxobismuthate(III)

Cited by 3 publications

References 19 publications

Alkalimetall-Oxoantimonate: Synthesen, Kristallstrukturen und Schwingungsspektren von ASbO2 (A = K, Rb), A4Sb2O5 (A = K, Rb, Cs) und Cs3SbO4

Alkalimetall-Oxoantimonate: Synthesen, Kristallstrukturen und Schwingungsspektren von ASbO2 (A = K, Rb), A4Sb2O5 (A = K, Rb, Cs) und Cs3SbO4

Chapter 21. New compounds and structures

Alkaline metal oxoantimonates(III),A3[SbO3] (A= K or Cs)

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Alkaline metal oxoantimonates(III),A₃[SbO₃] (A= K or Cs)