2023
DOI: 10.1002/ange.202313738
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Kaskadenreaktionen von aryl‐substituierten terminalen Alkinen unter Beteiligung von in situ erzeugten α‐Imino‐Goldcarbenen

Qiaoying Sun,
Christopher Hüßler,
Justin Kahle
et al.

Abstract: An efficient, highly selective and divergent synthetic method to construct 2‐substituted indoles and aryl‐annulated carbazoles via the intermolecular generation of α‐imino gold carbenes from terminal alkynes or diynes in combination with sulfilimines is disclosed. Importantly, the tandem reaction is proposed to proceed through an intermolecular gold carbene generation/ C‐H annulation followed by the activation of a second alkyne leading to 6‐endo‐dig cyclization, which is significantly different from previous … Show more

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