Katalytische, milde und selektive Oxyfunktionalisierung von linearen Alkanen: aktuelle Herausforderungen

Abstract

Es besteht eine große Nachfrage nach selektiven Katalysatoren für die nachhaltige Oxidation von Alkanen, denn die in der Umwelt sehr häufig vorkommenden Alkane kçnnen dadurch in hçherwertige Verbindungen, z.B. Chemikalien oder synthetische Brennstoffe, umgewandelt werden. Für diese – kinetisch gesehen – schwierige Reaktion wurde in den letzten Jahrzehnten eine Vielzahl von chemischen und biologischen Katalysatoren entwickelt, was einen Uberblick über das Gebiet erschwert. Dieser Kurzaufsatz gibt zunächst eine Definitiondes idealen Katalysators für die Alkan-Oxyfunktionalisierung und behandelt dann die heute verfügbaren Katalysatoren, die einem solchen idealen Katalysator am nächsten kommen

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