2021
DOI: 10.1021/acs.iecr.1c02395
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Kinetic and Nonideal VLE Modeling for Transesterification Reactions from FFA and Methyl Acetate at High Temperature and Pressure Considering Volatilization Effects/Influence

Abstract: A model has been proposed considering the compounds’ volatilization influence in simultaneous nonideal phase equilibrium, reaction kinetics, and chemical equilibrium for batch transesterification reactions from free fatty acids at high pressure and temperature. Phase nonideality was modeled using the “φ – φ” method. Different kinetic and thermodynamic modeling approaches were applied and tested, and their parameters were estimated from the reaction data of oleic acid with methyl acetate catalyzed by niobium ph… Show more

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