2013
DOI: 10.1016/j.fuel.2012.09.075
|View full text |Cite
|
Sign up to set email alerts
|

Kinetic investigation on thermal decomposition of hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX) nanoparticles

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
3
1
1

Citation Types

3
46
1

Year Published

2015
2015
2024
2024

Publication Types

Select...
9
1

Relationship

0
10

Authors

Journals

citations
Cited by 68 publications
(50 citation statements)
references
References 23 publications
3
46
1
Order By: Relevance
“…T b is defined as the lowest temperature at which a specific charge may be heated without undergoing thermal runaway [37][38][39][40] T b may be calculated from inflammation theory and appropriate thermo-kinetic parameters, namely the activation energy, frequency factor and heat of reaction.…”
Section: Characteristic Temperatures Of Thermal Explosionmentioning
confidence: 99%
“…T b is defined as the lowest temperature at which a specific charge may be heated without undergoing thermal runaway [37][38][39][40] T b may be calculated from inflammation theory and appropriate thermo-kinetic parameters, namely the activation energy, frequency factor and heat of reaction.…”
Section: Characteristic Temperatures Of Thermal Explosionmentioning
confidence: 99%
“…The performance of solid rocket propellant is strongly dependent on the characteristics of thermal decomposition of RDX [3,4]. Researchers have done much work on studying how to improve the combustion performance by adjusting the particle characteristics of energetic materials [5]. Actually, besides the energetic material itself, more and more researchers pay their attention to the additives that can be used to improve the thermal decomposition performance of RDX.…”
Section: Introductionmentioning
confidence: 99%
“…The critical temperature of thermal explosion (T b ) is an important parameter to evaluate the thermal stability of an energetic compound because it is essential to insure the safe storage and process operations involving explosives, propellants, and pyrotechnics. [20,21] The value of T b of 558.5 K can be calculated by the following Equation (8): [22] T b = (E 0 -ΊE 0 2 -4E 0 RT p0 ) / 2R (8) where E 0 is the apparent activation energy obtained by Ozawa's method, R is the gas constant, and T p0 is the peak temperature corresponding to βǞ0, 551.3 K. The distribution of electronic density is an important indicator to express the chemical and physical properties of a molecule, [23] and the contour line map of the electronic density on compound A was drawn in Figure 4 using the Multiwfn program. [24] It is reported that heavy nucleus always possess high peaks due to the nuclear charge improving electron aggregation and then displays integral exponential attenuation towards all surrounding atoms.…”
Section: Articlementioning
confidence: 99%