Kinetic Regularities of Obtaining Electrolytic Nano-Coatings and Cobalt Composites With Refractory Metals

Abstract

Electrodeposition of composite coatings based on cobalt alloys from citratepyrophosphate electrolytes is investigated. The features of the co-reduction of cobalt with refractory metals (Mo, W, Zr) directly from the electrolyte solution are due to the mutual influence of thermodynamic and kinetic characteristics of alloy-forming components. Modern electrochemical technologies for surface treatment of titanium alloys to create protective, antifriction, dielectric, and catalytically active materials are considered. The physicochemical fundamentals of the processes of plasma-electrolytic formation of conversion and composite electrolytic coatings are highlighted. Separate stages of electrode reactions, regularities of the influence of electrolyte components, and electrolysis parameters on the composition, structure, and morphology of synthesized materials are examined in detail. Considerable attention is paid to improving the synthesis of multicomponent alloys and composites based on cobalt from aggregative stable and stable electrolyte solutions, and flexible control of the composition and functional properties of materials is an urgent scientific and technical problem, the solution of which is the presented study.