Kinetic study of hydrogen peroxide reaction with hydroxonitrilotri(methylenephosphonato)iron(III) complex

Rizkalla, Ε. N.; Mansour, Mohamed A.; Anis, Samy S.

doi:10.1007/bf01040607

Search citation statements

Order By: Relevance

Paper Sections

Select...

Iron(iii) Complexes2

Citation Types

Supporting

Mentioning

Contrasting

Year Published

2000

Publication Types

Select...

Article1

Relationship

Self Cite0

Independent1

Authors

Journals

Cited by 1 publication

(2 citation statements)

References 8 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…The presence of one water molecule remote from the phosphonate groups resulted in a faster water-H 2 O 2 exchange as compared to the slow aquation of [FeY(OH)] 6Ϫ . An extension of these studies using [Fe(NTMP)(OH)] 4Ϫ complex [see Structure (2)] [NTMP ϭ nitrilotris(methylene-phosphonate)] was done in nitrate media [112]. (1) (2) Structures (1) The rate was first order in both the [complex] and [H 2 O 2 ] and Ϫ0.5 in [H ϩ ].…”

Section: Iron(iii) Complexesmentioning

confidence: 99%

See 1 more Smart Citation

Kinetics and mechanisms of decomposition reaction of hydrogen peroxide in presence of metal complexes

Salem

El-Maazawi

Zaki

2000

Int. J. Chem. Kinet.

122

View full text Add to dashboard Cite

Section: Iron(iii) Complexesmentioning

confidence: 99%

“…(1) (2) Structures (1) The rate was first order in both the [complex] and [H 2 O 2 ] and Ϫ0.5 in [H ϩ ]. The high enthalpy and the large positive entropy of activation supported a mechanism where the electron transfer step is rate determining [112].…”

Section: Iron(iii) Complexesmentioning

confidence: 99%