1990
DOI: 10.1021/j100373a053
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Kinetic study of the reaction potassium + oxygen + M (M = nitrogen, helium) from 250 to 1103 K

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Cited by 25 publications
(18 citation statements)
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“…The preexponential factor of eq 2 is close to the gas kinetic rate coefficient, as has also been observed for other metal atom reactions with HCl, specifically Al, 32 Cr, 33 Li, 34 Na, 35,36 and K. 37 These reactions are normally assumed to proceed as abstraction reactions, but some could conceivably also have an insertion channel. …”
Section: Discussionsupporting
confidence: 68%
“…The preexponential factor of eq 2 is close to the gas kinetic rate coefficient, as has also been observed for other metal atom reactions with HCl, specifically Al, 32 Cr, 33 Li, 34 Na, 35,36 and K. 37 These reactions are normally assumed to proceed as abstraction reactions, but some could conceivably also have an insertion channel. …”
Section: Discussionsupporting
confidence: 68%
“…As shown in Figure 1, K atoms are oxidized by O 3 to yield KO, which a second O 3 can then oxidize to KO 2 [Plane, 2002]. KO 2 also forms directly from the recombination of K and O 2 [Plane et al, 1990]. However, in the MLT these oxides exist in the presence of O, H, H 2 , H 2 O, and CO 2 .…”
Section: Theoretical Calculations On Neutral K Chemistrymentioning
confidence: 99%
“…In Fig. 6, the measured k1(T) are compared to k(T) of the neutral Ca [36,37] and K [26,27] reactions with O2…”
Section: Discussionmentioning
confidence: 99%