Kinetics and mechanism of oxidation of allyl, crotyl and cinnamyl alcohol by chromium(V)

Sreelatha, G; Rao, M. P.; Sethuram, B.; Rao, T. Navaneeth

doi:10.1007/bf01032227

Cited by 8 publications

(7 citation statements)

References 5 publications

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“…Peroxomonosulfate is a potential oxidant, and a large number of kinetic studies by peroxomonosulfate are reported in acidic and alkaline media . The kinetics of oxidation of unsaturated alcohols such as crotyl alcohol (CrA) by sodium bis[‐2‐ethyl‐2‐hydroxybutanato(2‐)] oxochromate(V) has been reported. The oxidation of crotyl alcohol in aqueous methanol by N ‐bromosuccinimide indicates rate independence of the hydrogen ion concentration.…”

Section: Introductionmentioning

confidence: 99%

Kinetics and Mechanism of Electron Transfer Reactions: Oxidation of Crotyl Alcohol by Peroxomonosulfate in Aqueous Acidic Medium

Sharma

Sailani

Meena

et al. 2018

Int J of Chemical Kinetics

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The kinetics and mechanism of oxidation of crotyl alcohol by peroxomonosulfate has been studied, and the species of the peroxomonosulfate are discussed to find out the role of activated species. A plausible reaction mechanism is suggested, and a derived rate law corresponds to all experimental observations. The activation parameters such as energy and entropy of activation have been calculated as 37.21 ± 0.5 kJ mol−1 and −148.91 ± 2.7 J K−1 mol−1, respectively, by employing the Eyring plot.

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Section: Introductionmentioning

confidence: 99%

Kinetics and Mechanism of Electron Transfer Reactions: Oxidation of Crotyl Alcohol by Peroxomonosulfate in Aqueous Acidic Medium

Sharma

Sailani

Meena

et al. 2018

Int J of Chemical Kinetics

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“…The absence of the Cr(V) signature at 510 nm in the UV-visible spectra during chemical degradation may be due to the fast and full reduction of Cr(V) to Cr(III), as reported in Equation (2d) [20].…”

Section: Equilibria Thermodynamic Constants At 25 °Cmentioning

confidence: 99%

“…In this scheme, the oxidation of 1-tridecanol (RCH 2 The absence of the Cr(V) signature at 510 nm in the UV-visible spectra during chemical degradation may be due to the fast and full reduction of Cr(V) to Cr(III), as reported in Equation (2d) [20]. The oxidation of 1-tridecanol by Cr(VI) can lead to the formation of 1-tridecanal and Cr(IV), as reported in Scheme 1 [12].…”

Section: Equilibria Thermodynamic Constants At 25 °Cmentioning

confidence: 99%

“…Subsequent degradation of the amine oxide via a 5-membered intermediate generates the A possible mechanistic scenario to account the formation of secondary amines as degradation products is presented in Scheme 3, where R 3 NH + is the protonated form of TOA (org and aq denote the organic phase and the aqueous phase, respectively) [ The absence of the Cr(V) signature at 510 nm in the UV-visible spectra during chemical degradation may be due to the fast and full reduction of Cr(V) to Cr(III), as reported in Equation (2d) [20]. The oxidation of 1-tridecanol by Cr(VI) can lead to the formation of 1-tridecanal and Cr(IV), as reported in Scheme 1 [12].…”

Section: Scheme 2 Aldehyde Oxidation Mechanisms (R = Tridecyl)mentioning

confidence: 99%

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Chemical Degradation of a Mixture of tri-n-Octylamine and 1-Tridecanol in the Presence of Chromium(VI) in Acidic Sulfate Media

Chagnes

Cote

2018

Metals

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Abstract:The chemical degradation of an extraction solvent composed of a mixture of tri-n-octylamine (extractant) and 1-tridecanol (phase modifier) in n-dodecane in contact with an acidic aqueous sulfate solution containing chromium(VI) has been investigated. The kinetics of degradation and the degradation products have been determined. GC-MS analyses evidenced the formation of 1-tridecanal, di-n-octylamine, N,N,N-octen-1-yl-dioctylamine, and an unidentified degradation compound, which may have contained a double bond and a carboxylic acid function. The mechanisms of degradation have been discussed on the basis of these identified degradation compounds. The study of the degradation kinetics showed that an increase of tri-n-octylamine concentration in the organic phase is responsible for a decrease of the degradation rate, while an increase in sulfuric acid concentration in the aqueous phase leads to a strong increase in the degradation rate.

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“…The structure of QnCC is given below, production of glycerol and also used as a precursor to many specialized compounds. The kinetics and mechanism of oxidation of allyl alcohol by various oxidants have been reported [2][3][4][5][6][7][8][9][10][11][12] . The kinetics of oxidation of allyl alcohol by QnCC has not been reported by investigation.…”

Section: Introductionmentioning

confidence: 99%

Kinetics of Oxidation of Allyl Alcohol by Cr(VI)

Sekar¹,

Palanivel²

2012

Orientjchem.

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The kinetics of oxidation of allyl alcohol by quinaldinium chlorochromate is investigated in 40 % acetic acid -water (v/v) medium. The order with respect to oxidant and hydrogen ion concentration is found to be one and fractional with respect to substrate. The rate of the reaction is decreases with the decrease in the dielectric constant of the medium. The rate of the reaction has negligible effect with the increase of ionic strength. The reaction does not induce the polymerization of acrylonitrile. From the kinetic data obtained, the activation parameters have been calculated and a plausible mechanism has been proposed.

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Kinetics and mechanism of oxidation of allyl, crotyl and cinnamyl alcohol by chromium(V)

Cited by 8 publications

References 5 publications

Kinetics and Mechanism of Electron Transfer Reactions: Oxidation of Crotyl Alcohol by Peroxomonosulfate in Aqueous Acidic Medium

Kinetics and Mechanism of Electron Transfer Reactions: Oxidation of Crotyl Alcohol by Peroxomonosulfate in Aqueous Acidic Medium

Chemical Degradation of a Mixture of tri-n-Octylamine and 1-Tridecanol in the Presence of Chromium(VI) in Acidic Sulfate Media

Kinetics of Oxidation of Allyl Alcohol by Cr(VI)

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