1986
DOI: 10.1149/1.2108667
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Kinetics and Mechanism of Silver Chloride Electroformation during the Localized Electrodissolution of Silver in Solutions Containing Sodium Chloride

Abstract: The electroformation of normalAgCl during electro‐oxidation of Ag in neutral normalNaCl solutions is investigated by using potentiostatic and potentiodynamic techniques complemented with SEM observation and EDAX. The kinetics of the electroformation of normalAgCl is interpreted through a complex model that implies the formation of adsorbed normalAgCl species at the submonolayer level, the electrodissolution of Ag through the normalAgCl submonolayer diffusing out of the electrode as a complex ion, and… Show more

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Cited by 34 publications
(18 citation statements)
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“…In the KCl solution with 4.0 mM KNO 3 , peak 2 and peak 5 shifted to −0.13 V and −0.30 V respectively and both of their shapes narrowed. The peak potentials are consistent with the values reported by De Mele et al 25 in 0.09 M NaCl, 0.91 M NaClO 4 solution at 0.02 V s −1 . The formation and stripping of silver chloride on a silver electrode were seen at ca.…”
Section: Resultssupporting
confidence: 91%
“…In the KCl solution with 4.0 mM KNO 3 , peak 2 and peak 5 shifted to −0.13 V and −0.30 V respectively and both of their shapes narrowed. The peak potentials are consistent with the values reported by De Mele et al 25 in 0.09 M NaCl, 0.91 M NaClO 4 solution at 0.02 V s −1 . The formation and stripping of silver chloride on a silver electrode were seen at ca.…”
Section: Resultssupporting
confidence: 91%
“…Similar features in a CV response were attributed to a 3D growth of AgCl for Ag/AgCl interfaces in various electrolytes [30,41,42]. However, to be noted is that AgCl is known to have a limited electron conductivity, together with a limited ionic conductivity (e.g., for Ag ?…”
Section: Testsmentioning
confidence: 59%
“…Both analytical and experimental works are reported and readily available [7,9,[30][31][32][33][34]. Studying these processes generally means recording the metal's response to a variety of imposed signals (waves).…”
Section: Testsmentioning
confidence: 99%
“…The strength of the acids correlates with the fact that the probability of H-bonding increases in the order H,PO; > HSOi = ClO; [19,24]. This influence of the strength of the acids has also been observed qualitatively for other reactions such as H-adatom electroadsorption-electrodesorption, and the more complicated electrooxidation of glucose residues on platinum in acids [25].…”
Section: Mechanistic Interpretationmentioning
confidence: 71%