Kinetics and mechanisms of adsorption/desorption of the ionic liquid 1‐buthyl‐3‐methylimidazolium bromide into mordenite

Chanie, Yewilsaw; Dı́az, Isabel; Pérez, Eduardo

doi:10.1002/jctb.4632

Cited by 10 publications

(7 citation statements)

References 21 publications

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“…All of these works [41,42,43,44,45,46,47,48,49,50] concluded that K2 better described the experimental kinetic data, except in ref. [49] in which K1 gave a better fit in the case of As(V) adsorption (while K2 was more satisfactory in the case of Cr(III) and Cr(VI)).…”

Section: Data Reported In 2015mentioning

confidence: 99%

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On the comparison of pseudo-first order and pseudo-second order rate laws in the modeling of adsorption kinetics

Simonin

2016

Chemical Engineering Journal

1,536

519

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In most works in the current literature about liquid/solid adsorption kinetics, the respective abilities of pseudo-first order and pseudo-second kinetics for describing the data are compared. In nearly all cases, it is concluded that the latter surpasses the former. The aim of this work is to point out that more caution should be exercised in this comparison. Indeed, it appears that the method generally used is flawed and that it unfairly favors pseudo-second order kinetics. A different method is proposed to analyze experimental results. It is employed here to reexamine experimental data taken from the literature.

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Section: Data Reported In 2015mentioning

confidence: 99%

“…Among these publications 4 could not be used because all of the data were at equilibrium [41,42,43,44]. As a consequence, these studies unsurprisingly reported better performance of K2 over K1 as noted in section 3.1.…”

Section: Data Reported In 2015mentioning

confidence: 99%

On the comparison of pseudo-first order and pseudo-second order rate laws in the modeling of adsorption kinetics

Simonin

2016

Chemical Engineering Journal

1,536

519

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“…ILs have been implemented in a wide range of industrial applications, including fuel cells [85], solar cells [86], batteries [87], and sensors [127] due to their unique properties such as low volatility, non-flammability, high thermal stability, and high ionic conductivity [128][129][130][131][132]. ILs are liquids comprised completely of ions from salts, which have a melting point below 100 • C. There are many sub-categories of ILs, including room temperature ILs, task-specific ILs, polyionic liquids, and supported IL membranes [131].…”

Section: Ionic Liquid (Il) Conjugated Echsmentioning

confidence: 99%

Rational design of microfabricated electroconductive hydrogels for biomedical applications

Walker

Portillo-Lara

Mogadam

et al. 2019

Progress in Polymer Science

167

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Electroconductive hydrogels (ECHs) are highly hydrated three-dimensional (3D) networks generated through the incorporation of conductive polymers, nanoparticles, and other conductive materials into polymeric hydrogels. ECHs combine several advantageous properties of inherently conductive materials with the highly tunable physical and biochemical properties of hydrogels. Recently, the development of biocompatible ECHs has been investigated for various biomedical applications, such as tissue engineering, drug delivery, biosensors, flexible electronics, and other implantable medical devices. Several methods for the synthesis of ECHs have been reported, which include the incorporation of electrically conductive materials such as gold and silver nanoparticles, graphene, and carbon nanotubes, as well as various conductive polymers (CPs), such as polyaniline, polypyrrole, and poly(3,4-ethylenedioxyythiophene) into hydrogel networks. These electroconductive composite hydrogels can be used as scaffolds with high swellability, tunable mechanical properties, and the capability to support cell growth both in vitro and in vivo. Furthermore, recent advancements in microfabrication techniques such as 3D bioprinting, micropatterning, and electrospinning have led to the development of ECHs with biomimetic microarchitectures that reproduce the characteristics of the native extracellular matrix (ECM). The combination of sophisticated synthesis chemistries and modern microfabrication techniques have led to engineer smart ECHs with advanced architectures, geometries, and functionalities that are being increasingly used in drug delivery systems, biosensors, tissue engineering, and soft electronics. In this review, we will summarize different strategies to synthesize conductive biomaterials. We will also discuss the advanced microfabrication techniques used to fabricate ECHs with complex 3D architectures, as well as various biomedical applications of microfabricated ECHs.

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“…These models are the most commonly used to describe the sorption of dyes. They include all steps of adsorption such as external film diffusion, adsorption, and internal particle diffusion (Chanie et al 2015).…”

Section: Kinetics Studymentioning

confidence: 99%

Valorization of the Spent Biomass of Pleurotus mutilus Immobilized as Calcium Alginate Biobeads for Methylene Blue Biosorption

et al. 2016

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The production of antibiotics in Algeria generates large amounts of residual biomass that should be considered a valuable biosorbent rather than waste. The aim of this work was to assess the use of antibiotic by-product biomass as a biosorbent for methylene blue removal from wastewater. Therefore, the biosorption of the cationic dye methylene blue by spent biomass of Pleurotus mutilus immobilized as calcium alginate biobeads (CAB) was studied in batch and column modes. The maximum uptake capacity was found to be 23 mg/g at a pH value of 10. Methylene blue biosorption by CAB was found to be spontaneous and exothermic. The adsorption capacity of the used biobeads was regenerated in continuous mode by washing the CAB with HCl (0.5 M) solution. Globally, this work showed the high potential of CAB made with spent biomass of P. mutilus as a biosorbent for the treatment of water contaminated with methylene blue.

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Kinetics and mechanisms of adsorption/desorption of the ionic liquid 1‐buthyl‐3‐methylimidazolium bromide into mordenite

Cited by 10 publications

References 21 publications

On the comparison of pseudo-first order and pseudo-second order rate laws in the modeling of adsorption kinetics

On the comparison of pseudo-first order and pseudo-second order rate laws in the modeling of adsorption kinetics

Rational design of microfabricated electroconductive hydrogels for biomedical applications

Valorization of the Spent Biomass of Pleurotus mutilus Immobilized as Calcium Alginate Biobeads for Methylene Blue Biosorption

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