2016
DOI: 10.1016/j.molliq.2016.09.012
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Kinetics and thermodynamic parameters of ionic liquid pretreated rubber wood biomass

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Cited by 83 publications
(21 citation statements)
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“…Previous research has proved that ILs have many advantages, including non-volatility, non-flammability, high thermal and chemical stability, wide electrochemical window, tunable miscibility, and good extraction capability, which are not attained for the volatile organic solvents [6][7][8]. As a result of these features and advantages, ILs are used in a wide range of applications such as catalyst [9][10][11][12][13][14], pre-treatment of biomass [15][16][17], absorbent [18][19][20], gas sensors [21], electrolyte [22][23][24], and membrane separation [25][26][27]. Among all of the applications, high-temperature utilization accounts for the vast majority, including high-temperature lubricants [28][29][30], solvents for high-temperature organic reactions [31], heat-transfer fluids [32,33], and thermal energy storage [34,35].…”
Section: Introductionmentioning
confidence: 99%
“…Previous research has proved that ILs have many advantages, including non-volatility, non-flammability, high thermal and chemical stability, wide electrochemical window, tunable miscibility, and good extraction capability, which are not attained for the volatile organic solvents [6][7][8]. As a result of these features and advantages, ILs are used in a wide range of applications such as catalyst [9][10][11][12][13][14], pre-treatment of biomass [15][16][17], absorbent [18][19][20], gas sensors [21], electrolyte [22][23][24], and membrane separation [25][26][27]. Among all of the applications, high-temperature utilization accounts for the vast majority, including high-temperature lubricants [28][29][30], solvents for high-temperature organic reactions [31], heat-transfer fluids [32,33], and thermal energy storage [34,35].…”
Section: Introductionmentioning
confidence: 99%
“…where ∆G * (J mol -1 ), ∆H * (J mol -1 ) and ∆S * (J mol -1 °C -1 ) are the changes in Gibbs free energy, enthalpy, and entropy of activation, respectively, B κ represents the Boltzmann constant (1.381×10 -23 J K -1 ), and h is the Plank constant (6.626×10 -34 J s -1 ). [46]. The ∆G * values of pinewood torrefaction slightly increased with increasing temperature, which indicated that the spontaneity in the torrefaction decomposition reaction increased at higher temperatures.…”
Section: Figure 6 Sse Values For Various Lnk0 and Ea Values With Considering Experimental Data At All Temperatures Simultaneouslymentioning
confidence: 88%
“…and organic or inorganic anions ( Zhang et al, 2012 ; Khan et al, 2021 ), and present as liquid phase at room temperature. Due to its efficiency on selective dissolution of lignin and cellulose ( Muhammad et al, 2015 ; Khan et al, 2016 ; Xu and Wang, 2020 ), renewability, and biodegradability, ILs are widely applied to separate the major components of lignocellulosic biomass ( Kilpeläinen et al, 2007 ; Hou et al, 2012 , 2013 ; Xu et al, 2018 ). Compared with ordinary solvents, ILs have the characteristics of being less volatile, and having lower vapor pressure, higher electrochemical stability, and higher thermal stability ( Khan et al, 2021 ).…”
Section: Traditional Pretreatment Methodsmentioning
confidence: 99%