Kinetics of acrylonitrile adsorption from an aqueous solution using Dowex Optipore L-493

Wegmann, C Christine; Garcia, Emanuel S.; Kerkhof, Pjam Piet

doi:10.1016/j.seppur.2011.08.017

Cited by 14 publications

(12 citation statements)

References 16 publications

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“…Experimental studies on liquid systems are listed in Table 4. We have not included papers that refer to the experimental setups as liquid ZLC systems, see for example (Babić et al 2008;Wegmann et al 2011), when these are in fact batch adsorption experiments where a short bed is placed in a liquid circulation loop. The relatively small number of systems included points to the difficulty in achieving good results in liquid systems.…”

Section: Range Of Applicationsmentioning

confidence: 99%

The zero length column technique to measure adsorption equilibrium and kinetics: lessons learnt from 30 years of experience

Brandani

Mangano

2020

Adsorption

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The zero length column technique has been developed over the past 30 years as a versatile experimental method to measure adsorption equilibrium and kinetics. In this review we discuss in detail the theory that forms the basis for the technique in order to understand how to design and operate efficiently a system. Experimental checks that should be performed to ensure the correct interpretation of the dynamic response are presented and examples are used to identify how to avoid major errors in determining diffusion time constants. The review concludes with an overview of all experimental studies available in the literature to date and a set of recommendations that should help improve the standard in the reported equilibrium and kinetic properties.

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Section: Range Of Applicationsmentioning

confidence: 99%

The zero length column technique to measure adsorption equilibrium and kinetics: lessons learnt from 30 years of experience

Brandani

Mangano

2020

Adsorption

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“…Taking the apparent density and pore volume of the dry form it was possible to estimate the particle porosity multiplying each other and getting the value of 0.394 close enough to the one reported in the literature, i.e., 0.35 [32]. Two steps are necessary to carry out the preparation of the resin, namely washing and drying.…”

Section: Methodsmentioning

confidence: 75%

Kinetic and equilibrium adsorption parameters estimation based on a heterogeneous intraparticle diffusion model

Silva

Muñoz-Peña

Domínguez

et al. 2021

Surfaces and Interfaces

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“…In that case, long times are required to reach equilibrium adsorption capacity and adsorption kinetics are slow. However, since the pores of Optipore are well connected, adsorption kinetics are assumed to be fast, as was also observed by Wegmann et al 7 for the removal of acrylonitrile from water using Optipore. In addition to our previous study where we investigated static equilibrium adsorption behavior, we here investigate the adsorption kinetics of the adsorption of HMF in Optipore, which are essential to design a process for practical application.…”

Section: -5 Adsorption Of Furans Is Established Bymentioning

confidence: 89%

Section: Introductionmentioning

confidence: 91%

Adsorption kinetics of Dowex^TM Optipore^TM L493 for the removal of the furan 5‐hydroxymethylfurfural from sugar

IJzer

Vriezekolk

Nijmeijer

2015

J of Chemical Tech & Biotech

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BACKGROUND Recently much research has been focused on the production and refinery of biobased fuels. The production of biofuels derived from lignocellulosic biomass is recognized as a promising route to produce biobased fuels responsibly. Often, product streams (e.g. glucose) still contain small amounts of undesired components (e.g. furans such as HMF). This study focuses on the removal of furans produced during the fermentation. In earlier work, styrene based resins have been identified as promising materials for this separation. In this work the kinetic properties of the most promising resin: DowexTM OptiporeTM L493 are studied. RESULTS The diffusion coefficient of 5 mg L−1 HMF was ∼8 × 10−12 m2 s−1 in water and 3.0 × 10−12 m2 s−1 in a glucose solution. The reduced diffusion coefficient in the particle when glucose is present is caused by the higher viscosity of the glucose solution and it indicates that diffusion is controlled by surface and pore diffusion. The breakthrough curves of HMF on Optipore showed that the column is very efficient under conditions of interest. CONCLUSION This study shows that Optipore is a much more efficient resin for HMF removal than currently used resins. Its fast kinetics and capacity make it possible to efficiently remove HMF from glucose solutions. © 2015 Society of Chemical Industry

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Kinetics of acrylonitrile adsorption from an aqueous solution using Dowex Optipore L-493

Cited by 14 publications

References 16 publications

The zero length column technique to measure adsorption equilibrium and kinetics: lessons learnt from 30 years of experience

The zero length column technique to measure adsorption equilibrium and kinetics: lessons learnt from 30 years of experience

Kinetic and equilibrium adsorption parameters estimation based on a heterogeneous intraparticle diffusion model

Adsorption kinetics of Dowex^TM Optipore^TM L493 for the removal of the furan 5‐hydroxymethylfurfural from sugar

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Kinetics of acrylonitrile adsorption from an aqueous solution using Dowex Optipore L-493

Cited by 14 publications

References 16 publications

The zero length column technique to measure adsorption equilibrium and kinetics: lessons learnt from 30 years of experience

The zero length column technique to measure adsorption equilibrium and kinetics: lessons learnt from 30 years of experience

Kinetic and equilibrium adsorption parameters estimation based on a heterogeneous intraparticle diffusion model

Adsorption kinetics of DowexTM OptiporeTM L493 for the removal of the furan 5‐hydroxymethylfurfural from sugar

Contact Info

Product

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Adsorption kinetics of Dowex^TM Optipore^TM L493 for the removal of the furan 5‐hydroxymethylfurfural from sugar