2014
DOI: 10.1016/j.ijggc.2014.04.023
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Kinetics of carbon dioxide binding by 1,1,3,3-tetramethylguanidine in 1-hexanol

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Cited by 34 publications
(21 citation statements)
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“…1.58 equivalents of TMG (from 5 possible) were converted into carbamates, as determined by weighing the mass of CO 2 uptake and considering the fraction converted into carbonates. This result is supported by the work of Ozturk et al 19 who performed a kinetic study of the reaction between CO 2 , TMG and 1-hexanol, with the formation of a carbamate intermediate product (reaction with TMG), stabilized by the alcohol. The authors proposed two alternative products: TMGCO 2 -+ TMGH + + hexanol and the other configuration HexCO 3 -+ TMGH + + hexanol.…”
Section: Figuresupporting
confidence: 59%
“…1.58 equivalents of TMG (from 5 possible) were converted into carbamates, as determined by weighing the mass of CO 2 uptake and considering the fraction converted into carbonates. This result is supported by the work of Ozturk et al 19 who performed a kinetic study of the reaction between CO 2 , TMG and 1-hexanol, with the formation of a carbamate intermediate product (reaction with TMG), stabilized by the alcohol. The authors proposed two alternative products: TMGCO 2 -+ TMGH + + hexanol and the other configuration HexCO 3 -+ TMGH + + hexanol.…”
Section: Figuresupporting
confidence: 59%
“…Orhan et al found that the termolecular mechanism is appropriate by applying theoretical DFT calculations. Ozturk et al have done a considerable amount of work with nonaqueous reactive solvents and found that the termolecular mechanism fitted data well. Ume et al studied an aqueous blend of amine solutions of N ‐(2‐hydroxethyl) piperazine and 2‐amino‐2‐hydroxymethyl‐1,3‐propanediol by using a termolecular reaction mechanism and achieved good results.…”
Section: Reaction Mechanism and Kinetics Modelsmentioning
confidence: 99%
“…These are the zwitterions mechanism, originally proposed by Caplow in 1968, and then reintroduced by Danckwerts in 1979 and termolecular reaction mechanism proposed by Crooks and Donnellan (1989) and modified by Ozturk et al (2014).…”
Section: Discussionmentioning
confidence: 99%