Kinetics of Coupled Heterogeneous Catalytic Reactions

Beránek, L.

doi:10.1016/s0360-0564(08)60479-4

Cited by 16 publications

(3 citation statements)

References 82 publications

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“…The limited computational possibilities restrained the estimation part of this work, in particular also the statistical tests which are considered nowadays as a necessary ingredient of modeling. Mention should be made also of work by Beranek (1975). Recently, Vanhove and Froment (to be published) investigated the air oxidation of o-xylene on a VzO5 catalyst in a tubular reactor of the integral type.…”

Section: Compkx Reactionrmentioning

confidence: 99%

Model discrimination and parameter estimation in heterogeneous catalysis

Froment¹

1975

AIChE Journal

116

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After a brief discussion of the experimental aspects of a kinetic investigation, the paper reviews the methodology of kinetic analysis, for both single and complex reactions. The necessity of statistical testing of the results is emphasized. Special attention is given to methods for estimating parameters in algebraic and differential equations. Sequential methods for the design of an experimental program aiming at optimal discrimination between rival models and optimal parameter estimation are reviewed and illustrated by means of practical examples.

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Section: Compkx Reactionrmentioning

confidence: 99%

Model discrimination and parameter estimation in heterogeneous catalysis

Froment¹

1975

AIChE Journal

116

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“…As the study of the oxidation of the different compounds alone cannot provide enough information to elucidate the reaction mechanism, the competing-reaction method has been employed. The study of the kinetics of coupled systems makes it possible to investigate the mutual influence of the reactions, highlighting the effects of eventual parallel reaction pathways, and can yield additional information about interaction between the reactants and the catalyst surface (Pyatnitskii, 1974;Beránek, 1975).…”

Section: Introductionmentioning

confidence: 99%

Deep Catalytic Oxidation of Aromatic Hydrocarbon Mixtures: Reciprocal Inhibition Effects and Kinetics

Barresi¹,

Baldi²

1994

Ind. Eng. Chem. Res.

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“…As the solvent adsorption on the catalyst is weak, it is convenient to use initial thymol mole fraction equal to unity NA = Ni = 1 at t = 0 (35) and integrating eq 34, the following equation was we can arrive at the stereoselectivity expressions for reaction products which do not contain time as a parameter (Beránek, 1975).…”

Section: Resultsmentioning

confidence: 99%