Phase pure and nano-sized hafnium diboride (HfB 2) fine powder was prepared via a novel sustainable silicothermic route at 1100°C from inexpensive raw materials HfO 2 , Na 2 B 4 O 7 and Si. By introducing sodium oxysalts as source of Na 2 O into the batch mixtures, the SiO 2 / Na 2 O modulus in the melt were reduced from