A comprehensive study is made of the radiative properties of boron plasma under conditions expected to be found in magnetic fusion devices. A detailed level-to-level model for all ionization stages of boron is used to perform collisional-radiative modelling at an electron density of 10 14 cm −3 for a range of electron temperatures. The ionization balance and radiative power loss are presented as a function of electron temperature, as well as emission spectra at selected temperatures. We show how a detailed level-to-level approach is required to obtain accurate ionization balances and power losses, especially at low temperatures. The calculations presented here should be of interest to the continuing efforts to model the radiative losses in large magnetic fusion devices, where thin boron films are sometimes considered as a plasma-facing material.