Kinetics of kukersite low-temperature pyrolysis in autoclaves

Identifying the reaction mechanism of oil-shale self-heating retorting by thermal analysis techniques

“…The correlation coefficients of the plottings for different processes shown in Table S1 support the assumption of first-order kinetics. First-order kinetics was also shown by many other reports involving the OS from various countries, such as Spain [40], Estonia [41], Morocco [33], Jordan [4,29], North Korea [3], USA [27,42], Parkistan [43], Turkey [42], etc [26,37]. Fig.…”

Formation and development of the pore structure in Chang 7 member oil-shale from Ordos Basin during organic matter evolution induced by hydrous pyrolysis

“…autoclave, sealed gold tubes and microscale sealed vessel) can simulate the quantity of gaseous hydrocarbon, the cracking of liquid hydrocarbon in higher temperature is also one part. Namely the overlap of primary and secondary reactions lie in the closed system [28][29][30]. Therefore, either open or closed system based experiments were limits to describe natural systems.…”

Effect of demineralization and heating rate on the pyrolysis kinetics of Jordanian oil shales

“…Several research groups [3][4][5][6][7][8][9][10][11][12][13][14][15][16] have modeled pyrolysis kinetics of oil shale utilizing data obtained from Thermogravimetric analysis, Differential Analyzers, Differential Scanning Calorimetry and RockEval Analyzers. Other workers [17][18][19][20] suggested kinetic models for cracking reactions and mass loss measurements.…”