Kinetics of liquid-phase oxidation of propionaldehyde with oxygen

Sandler, E.A.; Kharenko, Olesya A.; Ryabukhin, A. V.; Bobylev, B. N.

doi:10.1016/0031-6458(82)90022-3

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1988

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“…Chernyak and Andrianova [7] report on experimental results of the oxidation in chlorobenzene as solvent, in the temperature range between 10 and 30" C while Sandler et d . [8] carried out the oxidation in ethyl acetate at 30" C.…”

Section: Literature Surveymentioning

confidence: 99%

Kinetic analysis of the oxidation of isobutyraldehyde in liquid phase

et al. 1988

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The kinetics of non-catalytic as well as catalytic oxidation of isobutyraldehyde has been investigated. Reaction rate equations for the formation of the main product isobutyric acid and of the side products acetone, CO and CO, were derived. Kinetic parameters, namely the order of reaction, preexponential factor and activation energy were estimated by non-linear regression. The influence on selectivity and activity of the different types of catalysts employed was investigated quantitatively.

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Section: Literature Surveymentioning

confidence: 99%