Kinetics of the chloride anation reactions of cis- and trans-diaquodichloropalladate(II) in aqueous perchloric acid medium

Bekker, P. van Z.; Robb, W.

doi:10.1016/0022-1902(75)80546-x

Journal of Inorganic and Nuclear Chemistry

1975

DOI: 10.1016/0022-1902(75)80546-x

|View full text |Cite

Kinetics of the chloride anation reactions of cis- and trans-diaquodichloropalladate(II) in aqueous perchloric acid medium

P. van Z. Bekker¹,

W. Robb²

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

Supporting

Mentioning

Contrasting

Year Published

1975

2009

Publication Types

Select...

Article5

Relationship

Self Cite0

Independent5

Authors

Journals

Cited by 7 publications

References 20 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

Palladium‐catalyzed electroless plating of gold on latex particle surfaces

Kim

Daniels

Dimonie

et al. 2009

J of Applied Polymer Sci

View full text Add to dashboard Cite

Gold can be deposited onto a latex particle surface via the growth of metal islands with the electroless plating method. A new method is proposed for the electroless plating of gold on the surface of poly(styrene-covinylimidazole) latex particles, which is catalyzed by palladium present on the latex particle surfaces. The palladium ions are anchored to the latex particle surfaces by the formation of a palladium-imidazole complex, and palladium nanoparticles are nucleated by a reductant. These palladium islands act as catalytic sites, so gold is preferentially deposited onto the latex particle surfaces. Transmission electron microscopy, X-ray photoelectron spectroscopy, and sucrose density gradient column results indicate that the palladium is associated with the imidazole-functionalized latex particles. Different gold loading levels and reductant types were explored. Latex particles were partially encapsulated by finely dispersed gold nanoparticles less than 2 nm in diameter or by gold islands with sizes ranging from 10 to 100 nm up to a gold loading level of 3.1 mg of Au/m 2 of latex. However, using higher gold loading levels led to uncontrollable electroless plating of gold because gold reduction in the water phase became very dominant even in the presence of catalytic palladium on the latex particle surface.

show abstract

Palladium‐catalyzed electroless plating of gold on latex particle surfaces

Kim

Daniels

Dimonie

et al. 2009

J of Applied Polymer Sci

View full text Add to dashboard Cite

show abstract

Characterization of a colloidal Pd(II)-based catalyst dispersion for electroless metal deposition

Dressick

Kondracki

Chen³

et al. 1996

Colloids and Surfaces A: Physicochemical and Engineering Aspect

View full text Add to dashboard Cite

Aqua palladium complexes: synthesis, properties and applications

Vicente

Arcas

2005

Coordination Chemistry Reviews

100

View full text Add to dashboard Cite

scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.

Contact Info

customersupport@researchsolutions.com

10624 S. Eastern Ave., Ste. A-614

Henderson, NV 89052, USA

This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.

Blog Terms and Conditions API Terms Privacy Policy Contact Cookie Preferences Do Not Sell or Share My Personal Information

Made with 💙 for researchers

Part of the Research Solutions Family.

Kinetics of the chloride anation reactions of cis- and trans-diaquodichloropalladate(II) in aqueous perchloric acid medium

Cited by 7 publications

References 20 publications

Palladium‐catalyzed electroless plating of gold on latex particle surfaces

Palladium‐catalyzed electroless plating of gold on latex particle surfaces

Characterization of a colloidal Pd(II)-based catalyst dispersion for electroless metal deposition

Aqua palladium complexes: synthesis, properties and applications

Contact Info

Product

Resources

About