Kinetics of the Synthesis of Polystrene Glycols

Aghadjan, A.; Blanchard, L. P.; Baijal, M. D.

doi:10.1021/i360025a003

I&EC Product Research and Development

1968

DOI: 10.1021/i360025a003

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Kinetics of the Synthesis of Polystrene Glycols

A. Aghadjan¹,

L. P. Blanchard²,

M. D. Baijal³

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1969

1986

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Cited by 3 publications

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“…carried out by the method described earlier (1). The product obtained from the copolymerization when analyzed by GPC* was found to consist of three components a s shown in Figure 1.…”

mentioning

confidence: 98%

Cyclic dimer of styrene oxide in cationic copolymerization

Kondo

Blanchard

1969

J. Polym. Sci. B Polym. Lett.

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“…carried out by the method described earlier (1). The product obtained from the copolymerization when analyzed by GPC* was found to consist of three components a s shown in Figure 1.…”

mentioning

confidence: 98%

Cyclic dimer of styrene oxide in cationic copolymerization

Kondo

Blanchard

1969

J. Polym. Sci. B Polym. Lett.

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Polymerization of styrene oxide by nitronium tetrafluoroborate

Velichkova

Tsevi

1986

J. Polym. Sci. A Polym. Chem.

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SynopsisT h e polymerization of styrene oxide by nitronium tetrafluoroborate in nitromethane and methylene chloride at 5, 20, and 50°C is investigated. GPC analyses of the products combined with isocyanate method show that both cyclic and linear oligomers are formed. In CH,NO, the cyclic dimer and trimer are 2-benzyl-4-phenyl-l,3dioxolane and 1,3,5-tribenzyl-trioxane, respectively. In CH,CI, 2,5-diphenyldioxane is isolated. In nitromethane, mainly isomenxed structures with acetal linkage are produced, while in methylene chloride isomenistion does not proceed. Hy NMR and IR spectra the presence of C-0 and OH end groups in the hear oligomers is shown. There are indications that oligomers are formed both directly from the monomer and by degradation of the polymer.

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Cationic Copolymerization of Styrene Oxide with Propylene Oxide

Blanchard

Aghadjan

Malhotra

1975

Journal of Macromolecular Science: Part A - Chemistry

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Kinetics of the Synthesis of Polystrene Glycols

Cited by 3 publications

References 5 publications

Cyclic dimer of styrene oxide in cationic copolymerization

Cyclic dimer of styrene oxide in cationic copolymerization

Polymerization of styrene oxide by nitronium tetrafluoroborate

Cationic Copolymerization of Styrene Oxide with Propylene Oxide

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