Reaction rate model could be determined from kinetic characteristics. Kinetic and thermal decomposition of municipal solid waste (MSW) pellets, consist of organic material, plastic, paper and leaves, with tapioca flour as binder (0%, 3% and 6%) were studied in thermogravimetric analyzer from temperature 50°C to 800°C at heating rate 10 0C/min in N2 atmospheres. The kinetic parameter were determined by Model Fitting or Coats Redfern Methods with different kinetic reaction model. Results of this study have shown that MSW pellets in various binder has activation energy values 64.64 kJ/mol and 22.06 kJ/mol for 0%, 68.83 kJ/mol and 21.99 kJ/mol for 3%, and 69.29 kJ/mol and 22.62 kJ/mol for 6% at temperature ranges between 200°C-400°C and 400°C-500°C respectively in typical three dimensional diffusion (D3) mechanism kinetic reaction model.