We consider the following Choquard equationwhere λ is a real parameter, 2is the critical exponent in the sense of the Hardy-Littlewood-Sobolev inequality. Under some suitable assumptions on λ, µ, via the constrained minimizer method and concentration compactness principle, we prove that this system has multiple of solutions, and one of which is a positive ground state solution. Moreover, by using an abstract result due to K.-C Chang, we admit infinitely many pairs of distinct solutions. In addition, we prove the nonexistence result by Pohožaev identity when λ < 0. The main results extend and complement the earlier works in the literature.