In this note, we analyze several families of vertex algebras whose characters can be expressed using (generalized) q-MZVs. We analyze: (i) characters of vertex algebras associated to arc spaces, (ii) characters (or indices) of certain S-class VOAs in 4d N = 2 SCFT, (iii) supercharacters of the U family of vertex algebras. Along the way we also introduce a family of multiple q-zeta values associated to simple Lie algebras and present their conjectural properties.