Djohong municipality is located at the border between Eastern Cameroon and Central African Republic (CAR), in the Mbere division. The region is a shelter for thousands of people fleeing the socio-political crisis in CAR and it lacks safe drinking water supply. Surface water, rainwater, and shallow groundwater wells are the main water sources. As a result, deep aquifers appear to be an affordable solution to the widespread water demand gap in the region of Djohong. Forty-nine Schlumberger vertical electrical sounding (VES) were carried out in the framework of this study with maximum current electrode spacing of 240 m. The purpose was to investigate the occurrences of groundwater and related structural elements in the study area, which hosts two refugee camps, Ngam and Borgop. Eight geoelectric profiles were realized and their geological characteristics vary from the altered part to the bedrock, with ferruginous sediments and metaconglomerates in between. The altered part is composed of topsoil, travertines, sandy clay, clayey sand, and fractured shales with different geophysical characteristics. Two aquifer systems were highlighted, respectively in the altered soils of clayey sand and low permeability fractured rocks. The upper aquifer made of clayey sand is located in Ngam camp with thickness of 5 to 15 m and resistivity of 700 – 1500 Ω.m. The lower aquifer which is considered the main aquifer is located in both camps. It is hosted in the low permeability fractured shales of the Ngam camp, with resistivity of 200 to 1000 Ω.m and thickness of 34 to 82 m. In the Borgop camp, it occurs in the fractured granitic bedrock at about 8 and 19 m deep. Structurally, the study area is controlled by several potential faults, with NE – SW strike as a whole. The present study highlighted favourable conditions reducing geological and hydrogeological limitations to provision of safe drinking water for refugees of the two camps in Djohong.