The main goal of this work is to introduce the notion of Hom-M-dendriform algebras which are the dendriform version of Hom-Malcev algebras. In fact they are the algebraic structures behind the O-operator of Hom-pre-Malcev algebras. They also fit into a bigger framework as Hom-Malcev algebraic analogues of Hom-L-dendriform algebras. Furthermore, we show a connections between Hom-M-Dendriform algebras and Hom-alternative quadri-algebras.